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Why does toluene have a higher boiling point than methylcyclohexane?

Why does toluene have a higher boiling point than methylcyclohexane?

The higher vapour pressure of methylcyclohexane is a direct result of weaker intermolecular forces in the pure liquid state than those present between toluene molecules in its liquid state. In general, the strength of London (vdW) dispersion forces increases with the size of the molecules involved.

What causes something to have a high boiling point?

The boiling point of a liquid depends on the intermolecular forces present between the atoms or molecules in the liquid since you must disrupt those forces to change from a liquid to a gas. The stronger the intermolecular forces, the higher the boiling point.

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What explains high boiling point?

Water molecules in liquid state have the ability to form hydrogen bonds with each other. These hydrogen bonds are some of the strongest of all intermolecular forces, so a large amount of energy is needed to break these interactions − this is the main reason why water has such a high relative boiling point.

Does toluene or phenol have a higher boiling point?

Thus, due to intermolecular hydrogen bonding and polar nature of -OH group in phenol, they have higher boiling point points than toluene.

Does toluene have a high boiling point?

231.1°F (110.6°C)Toluene / Boiling point

Why toluene has higher boiling point than water?

Stronger intermolecular interactions means higher boiling points. Phenol and toluene have almost same molecular weight. Both have similar shape which means that intermolecular attraction due to van der waal’s dispersion force is going to be same.

Why do some substances have a high melting point?

When molecules are tightly packed together, a substance has a higher melting point than a substance with molecules that do not pack well. Molecular size also affects the melting point. When other factors are equal, smaller molecules melt at lower temperatures than larger molecules.

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What is the boiling point of CH3CH2OH?

78º
Ethanol, CH3CH2OH (mw=46) has a boiling point of 78º.

What intermolecular forces have the highest boiling point?

As you would expect, the strength of intermolecular hydrogen bonding and dipole-dipole interactions is reflected in higher boiling points.

What is the boiling point of toluene?

Why boiling point of aniline is higher than toluene?

But phenol do have intermolecular hydrogen bonding between the molecules which toluene lacks. This makes intermolecular attraction of phenol more than that of toluence. Hence phenol boils at higher temperature when compared to toluene. This is mainly due to the difference in molecular weight.

What is the boiling point of toluene at 600mm Hg?

The boiloing point of toluene at atmospheric pressure of 760 mm (torr) is 110.5 deg C. Reducing the pressure lowers the boiling point. The boiling point of toluene at 600 mm (torr) is 104.0 deg C.

What are the safety hazards of toluene?

Chemical Stability: Normally stable.

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  • Conditions to Avoid: Open flames,sparks,static discharge,heat and other ignition sources.
  • Incompatible Materials: Reacts violently with: nitric acid.
  • Hazardous Decomposition Products: None known.
  • Possibility of Hazardous Reactions: None known.
  • What are the health effects of toluene?

    Inhalation: Can irritate the nose and throat.

  • Skin Contact: SKIN IRRITANT.
  • Eye Contact: May cause mild irritation.
  • Ingestion: Can cause effects as described for inhalation.
  • Effects of Long-Term (Chronic) Exposure: Can cause dry,red,cracked skin (dermatitis) following skin contact.
  • Carcinogenicity: Not known to cause cancer.
  • Why is toluene used as a solvent?

    Toluene is mostly used as a solvent and an additive in gasoline to improve octane ratings. Toluene also produces other chemicals, such as benzoic acid , which is used as a preservative in foods, cosmetics and drinks.