Q&A

Is nitrobenzene a base or acid?

Is nitrobenzene a base or acid?

Now, in case of Nitrobenzene due to the presence of an electron-withdrawing group like −NO2 the acidity of the molecule increase as they increase the positive charge on the benzene ring, hence they show acidic character more rather than basic character.

What is nature of nitrobenzene?

Nitrobenzene is an industrial chemical. It is an oily yellow liquid with an almond-like odor. It dissolves only slightly in water and will evaporate to air. Most of the nitrobenzene produced in the United States is used to manufacture a chemical called aniline.

Is nitro basic or acidic?

The nitro group is one of the most common explosophores (functional group that makes a compound explosive) used globally. The nitro group is also strongly electron-withdrawing. Because of this property, C−H bonds alpha (adjacent) to the nitro group can be acidic.

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Why is nitrobenzene a weak base?

Secondly, aniline and p-nitroaniline (first two green shaded structures) are weaker bases due to delocalization of the nitrogen non-bonding electron pair into the aromatic ring (and the nitro substituent). This is the same delocalization that results in activation of a benzene ring toward electrophilic substitution.

Is nitrobenzene acidic in nature?

nitro group is a strong withdrawing group and deactivating also so the positive charge on the benzene increases….if the positive charge increases the acidic nature increases…. therefore nitrobenzene is more acidic than benzene….

What is nitrobenzene for?

Most of the nitrobenzene produced in the United States is used to manufacture a chemical called aniline. Nitrobenzene is also used to produce lubricating oils such as those used in motors and machinery. A small amount of nitrobenzene is used in the manufacture of dyes, drugs, pesticides, and synthetic rubber.

How does nitrobenzene reacts in acidic and basic medium?

In acidic medium if nitro benzene is reduced along with tin and concentrated HCl acid,then it is reduced or converted to aniline. When reduced in alkaline medium,nitro benzene forms some intermediate products like Nitrosobenzene and Phenyl hydroxylamine which undergo bi-molecular condensation reaction.

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Is nitrobenzene polar or nonpolar?

The log P value of nitrobenzene is 1.85, compared with -0.18 for the definitely polar molecule ethanol, and 3.66 for the non-polar molecule cumene. So it would be fair to say that nitrobenzene has some polar character, but it’s not a very polar molecule like the low molecular weight alcohols such as ethanol.

Is nitrobenzene an aromatic compound?

nitrobenzene, the simplest aromatic nitro compound, having the molecular formula C6H5NO2. Nitrobenzene is a colourless to pale yellow, oily, highly toxic liquid with the odour of bitter almonds.

What happens when nitrobenzene is reduced in acidic and neutral medium?

In a weakly acidic medium, nitrobenzene on electrolytic reduction gives aniline but under strongly acidic medium it gives p-aminophenol. In the alkaline medium, various mono and di-nuclear reduction products such as Azoxybenzene, Azobenzene are obtained. Therefore, the correct option is Option C, p-Aminophenol.

What happens when nitrobenzene reacts with Sn HCl?

Nitrobenzene is reduced to aniline by Sn and concentrated HCl. Aniline salt is given from this reaction. Then aqueous NaOH is added to the aniline salt to get released aniline. This reaction is called nitrobenzene reduction.

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Is nitrobenzene a polar solvent?

What is the meaning of nitrobenzene?

Nitrobenzene. Nitrobenzene is a yellowish, oily, aromatic nitro-compound with an almond-like odor that emits toxic fumes of nitrogen oxides upon combustion. Nitrobenzene is primarily used in the manufacture of aniline, but is also used in the manufacture of lubricating oils, dyes, drugs, pesticides, and synthetic rubber.

Are nitro compounds acidic or basic in nature?

Hence, all the nitro compounds are weakly acidic in nature. They dissolve in bases to give salts and can be regenerated by adding a stronger acid like HCl. Celebrity surgeon reveals how actresses keep skin tight.

Is benzene an acid or a base?

Firstly, Benzene on its own isn’t readily classified as an acid or basic, it’s entirely debatable. But, one can ( but I don’t) agree it is a Lewis base because it undergoes some substitution reactions. Now, however, when we are speaking about a group along with benzene, it changes the dynamic.

What are the characteristics of amphoteric oxides?

Amphoteric oxides are compounds of oxygen which exhibits both acidic as well as basic characteristics. These oxides when reacting with acid undergoes a neutralization reaction to form water and salt. This exhibits the basic property of the compounds.