Q&A

Does mass affect polarizability?

Does mass affect polarizability?

The more electrons a molecule contains, the higher its ability to become polar. Polarizability increases in the periodic table from the top of a group to the bottom and from right to left within periods. This is because the higher the molecular mass, the more electrons an atom has.

What factors affect polarizability?

Molecular orientation, atomic radii, and electron density are the main three factors that influence the Polarizability in the following way: As the number of electrons increases, the control on distribution of charge by the nuclear charges becomes less, and thus the Polarizability of atom increased.

How does size affect polarizability?

The biggest factor that effects the polarizability of a substance is the size of the material. Larger molecules, atoms, or ions are more polarizable than smaller objects.

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Does molar mass affect polarity?

Compare the molar masses and the polarities of the compounds. Compounds with higher molar masses and that are polar will have the highest boiling points.

What intermolecular forces increase with increasing molecular mass?

Dispersion forces tend to increase with increasing molar mass.

How does polarizability affect solubility?

Increase in solute dipolarity/polarizability increases solubility, whereas an increase in solute excess molar refraction, and especially, volume decrease solubility.

How does polarizability increase on the periodic table?

Generally, polarizability increases as the volume occupied by electrons increases. In atoms, this occurs because larger atoms have more loosely held electrons in contrast to smaller atoms with tightly bound electrons. On rows of the periodic table, polarizability therefore decreases from left to right.

How does bond strength affect polarizability?

If an anion has greater polarizability, then it will more likely be “sharing” its electrons with the cation that is exerting a force on its electrons; hence, molecules with anions having a greater polarizability are not necessarily stronger in bond strength; rather, it is simply more covalent in character.

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What factor affects the polarizability of a certain nonpolar molecule?

Factors that Influence Polarizability The greater the number of electrons, the greater the polarizability. The greater the distance of electrons from nuclear charge, the greater the polarizability of the atom.

How does mass affect intermolecular forces?

When the weight of individual gas molecules becomes significant, London dispersion forces, or instantaneous dipole forces, tend to increase, because as molecular weight increases, the number of electrons within each gas molecule tends to increase as well.

How does molecular mass affect the polarizability of an element?

When talking about elements in the same group, generally higher molecular mass increases polarizability due to increased number of electrons, and therefore would have a higher bp. This is why polarizability increases as you go down a column (AW increases). And N and O are similar enough that it too follows the molecular weight standard.

What is the relationship between polarizability and dispersion forces?

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The relationship between polarizability and dispersion forces can be seen in the following equation, which can be used to quantify the interaction between two like nonpolar atoms or molecules: α is the polarizability constant expressed in units of m 3. This expression of α is related to α ′ by the following equation:

What is linear polarizability of dipole moment?

The linear polarizability, α, describes the first-order response of the dipole moment with respect to external electric fields. The polarizability of a solute can be related to the dielectric constant of the solution through Debye’s equation and molar refractivity through the Clausius-Mosotti equation [1].

When an object becomes polarized it becomes a charged object?

When an object becomes polarized, it acquires a charge and becomes a charged object. When an object becomes polarized, its center of positive charge becomes separated from its center of negative charge. Overall, there are just as many positive charges as negative charges; the object has a balance of charges and is therefore neutral.