What is staggered conformation in chemistry?

In organic chemistry, a staggered conformation is a chemical conformation of an ethane-like moiety abcX–Ydef in which the substituents a, b, and c are at the maximum distance from d, e, and f. This requires the torsion angles to be 60°.

What is staggered and eclipsed conformation?

In an eclipsed conformation the carbons are aligned so that the hydrogens are lined up with each other. This creates steric hindrance between them. In a staggered conformation the atoms are all equally spaced from each other.

What are staggered conformers called?

anti
This particular staggered conformation is called anti. The other staggered conformation has a Me-Me dihedral angle of 60 degrees and is called gauche.

What is the difference between Gauche and staggered?

In Staggered Conformation, no group lies parallel to another one in a compound. In Gauche form, More bulky and less bulky groups lie parallel to each other.

What does staggered formation means?

An aircraft formation in which elements are at different levels and are not abreast of each other. One of the elements may be higher than the other and slightly behind or in front of it but to one side.

Is staggered conformation more stable?

hydrocarbons. …the least stable, and the staggered conformation is the most stable. The eclipsed conformation is said to suffer torsional strain because of repulsive forces between electron pairs in the C―H bonds of adjacent carbons.

What is conformation in organic chemistry?

conformation, any one of the infinite number of possible spatial arrangements of atoms in a molecule that result from rotation of its constituent groups of atoms about single bonds.

What is meant by skew conformation?

1 any conformation of a six‐membered ring form of a monosaccharide or monosaccharide derivative when three adjacent ring atoms and the remaining nonadjacent ring atom are coplanar.

What is skew conformation?

Skew conformations are infinite conformations in between the specific ones formed due to rotation along the bond but they are not anti,staggered, or gauche.

Why is staggered conformation more stable than eclipsed conformation?

The staggered conformation of ethane is a more stable, lower energy conformation than the eclipsed conformation because the eclipsed conformation involves unfavorable interactions between hydrogen atoms. Specifically, the negatively charged electrons in the bonds repel each other most when the bonds line up.

What is a staggered line?

To place on or as if on alternating sides of a center line; set in a zigzag row or rows: theater seats that were staggered for clear viewing. 4. To arrange in alternating or overlapping time periods: staggered the nurses’ shifts. 5.

What is staggered and eclipsed conformation in organic chemistry?

The two terms, Staggered and eclipsed conformation(two main branches of the Newmann projections) are used in Organic Chemistry to explain the arrangement of atoms in some organic molecules. In terms of stability, staggered conformation is more stable than eclipsed formation.

What is a staggered conformation?

Please help improve the article by providing more context for the reader. (March 2011) ( Learn how and when to remove this template message) In organic chemistry, a staggered conformation is a chemical conformation of an ethane -like moiety abcX–Ydef in which the substituents a, b, and c are at the maximum distance from d, e, and f.

What is meant by staggered conformation of ethane?

Staggered conformation is a chemical conformation of an ethane-like molecule (CH3-CH3=abcX–Ydef) in which the substituents a, b, and c are attached at the maximum distance from d, e, and f. In this case, the torsion angle is 60° and the conformational energy is minimum.

What is steric hindrance and staggered conformation?

Staggered – A conformation where bonds have dihedral angles of sixty degrees. This typically minimizes the energy. Steric hindrance – Repulsion between the electron clouds on bulky groups of a molecule or between molecules. Syn – Steric hindrance between terminal methyl groups in a system of at least five carbon centers.