Which is more reactive Methyl Chloride or chlorobenzene?

Answer: Methyl Chloride is more reactive than chlorobenzene.

Why is chlorobenzene less reactive than chloride?

In chlorobenzene, there are three lone pairs of electrons. These lone pairs on the chlorine undergo resonance with the πelectrons of the benzene ring. Due to this resonance the C-Cl bond acquires a double bond character in it. Therefore, chlorobenzene is less reactive than benzyl chloride.

Why chlorobenzene is less reactive than Methyl Chloride towards nucleophilic substitution reaction?

Chlorobenzene is less reactive towards nucleophilic substitution reaction because of the following reasons: This results in delocalization of the electrons of C – Cl bond and a partial double bond character develops in the bond, which makes it difficult for the Nucleophile to cleave the C – Cl bond.

Why chlorobenzene is less polar than Methyl Chloride?

Since sp2 has more s character and more electronegative than sp3. Also, In chlorobenzene resonance gives rise to partial double bond charcter to the carbon- halogen bond, making it stronger by reducing the polarity of the carbon -halogen bond. Hence, chlorobenzene is less polar than cyclohexyl chloride.

Why benzyl chloride is more reactive than methyl chloride?

Due to this resonance the C-Cl bond acquires a double bond character in it. Whereas in benzyl chloride, the loss of chlorine yields a benzyl carbocation, which is resonance stabilized. Hence it is more reactive.

Why vinyl chloride is less reactive than methyl chloride?

The resonance shown by vinyl chloride is as follows: In vinyl chloride, during this resonance the carbon chlorine bond aquires some double bond character which decreases it reactivity.

Why is methyl chloride hydrolysed than chlorobenzene?

Methyl chloride hydrolysed more easily than chlorobenzene. It is due to double bond character in chlorobenzene due to resonance which is difficult to break as compared to single bond (C—Cl) in CH3Cl.

Why ethyl chloride is more reactive than benzyl chloride?

Benzyl carbocation is stabilised by resonance hence, benzyl chloride easily gives nucleophilic substitution reaction than ethyl chloride…

Why is chlorobenzene less reactive than chloroethane?

In chlorobenzene the lone pair of halogen (i.e, here chlorine) is delocalised on aromatic ring, which lead to the formation of partial double bond character. As the Bond length is less for chlorobenzene that is 0.169nm bond length for chloroethane is 0.177nm, chlorobenzene is less reactive.

Which Halobenzene is more reactive towards nucleophilic substitution reaction?

Benzyl chloride is more reactive than chlorobenzene towards nucleophilic substitution.

Why are aryl halides less reactive than alkyl halides towards nucleophilic substitution reactions?

In aryl halides, one of the lone pairs of electrons on the halogen atom is in conjugation with π-electrons of the ring. Due to resonance, the C–X bond acquires partial double bond character. Therefore, aryl halides are less reactive than alkyl halides towards nucleophilic substitution reactions.

Why benzyl chloride is reactive?

Benzyl chloride on losing the chloride ions get a +ve charge on ring which can be easily stabilized by the resonance. And due to this, benzyl chloride is highly reactive towards SN1 reaction.

Why is the reactivity of benzyl chloride less than chlorobenzene?

Chlorobenzene is less reactive than benzyl chloride. In chlorobenzene the lone pairs present on C l atom get involved in resonance with π electrons of benzene due to which C −C l bond acquires double bond character Hence , reactivity decreases.

Why is chlorobenzene less reactive than alkyl halide?

Chlorobenzene is an aryl halide….aryl halides are less reactive than haloalkanes due to resonance stabilisation and sp2 hybridization of the carbon atoms of benzene rings Chlorobenzene is less reactive than alkyl halide..

Why are haloalkanes less reactive than Haloarenes?

CYCLOHEXYL CHLORIDE. Because haloarenes ( Chlorobenzene ) are less reactive than haloalkanes , towards SN reactions. This is due to many reasons, like double bond nature of C—Cl bond in chlorobenzene, due to resonance.

What is the Friedel-Crafts alkylation of chlorobenzene?

Yes, the reaction will proceed by Friedel-Crafts alkylation: Firstly, the Lewis acid catalyst abstracts the chloride ion from methyl chloride, giving a reactive, electrophilic methenium ion. Then, electrons from the system of the benzene ring of chlorobenzene then attack the electrophilic ion.