Q&A

Is entropy conserved in a reversible process?

Is entropy conserved in a reversible process?

Entropy is very different from energy. Entropy is not conserved but increases in all real processes. Reversible processes (such as in Carnot engines) are the processes in which the most heat transfer to work takes place and are also the ones that keep entropy constant.

Why is entropy not conserved?

As long as a system has the same number of atoms and the same number of quanta of energy to share between them, it is plausible that the system possesses a minimum number of possible microstates—and a minimum entropy. …

In what process does entropy remain constant?

Entropy always accompanies heat transfer. But there are also other source of entropy such as friction which are commonly called as irreversibilities. Hence for only reversible adiabatic process entropy remains constant also known as isentropic process.

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Is there a conservation law for entropy?

Conservation under certain conditions We have seen that certain physical quantities obey a conservation law: Energy, momentum, angular momentum, electric and magnetic charge. Others do not: entropy and amount of substance.

Why there is no change in entropy in a reversible adiabatic process?

As no heat is allowed to transfer between the surrounding and system, the heat remains constant. Thus The change in entropy between the S1 and S2 would be equal to zero. This is applicable for the only reversible adiabatic process. Therefore, the change in the entropy for an adiabatic process equals to zero.

What happens to entropy in an irreversible process?

An irreversible process increases the entropy of the universe. Because entropy is a state function, the change in entropy of the system is the same, whether the process is reversible or irreversible. This is just the same as if in a system one section of the gas was hot, and the other cold.

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Can entropy be created or destroyed?

Entropy, as thermal disorder, is always generated (produced), in all processes without exception, and cannot be destroyed (no “thermal order”) by any means. This should not be confused with local entropy change that could increase or decrease due to entropy transfer.

Is change in entropy a state function?

Entropy is a State Function because it depends only on the initial and final thermodynamic states and not on the path followed.

Does entropy change to zero?

Therefore, the entropy change of a system is zero if the state of the system does not change during the process. For example entropy change of steady flow devices such as nozzles, compressors, turbines, pumps, and heat exchangers is zero during steady operation.

Why does entropy remain constant in a reversible process?

Entropy remains constant in a reversible process because energy is not “degraded.” It is stored as potential energy in a form that can do enough work to restore the system plus surroundings to their initial conditions. The entropy is merely transferred from system to surroundings.

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What is the most important significance of entropy?

The most important significance of entropy is that it can be used to measure the randomness in the system.  Entropy Changes in Reversible Processes Suppose that the heat absorbed by the system and heat lost by the surrounding are under completely reversible conditions.

What is the net change in entropy of universe?

For reversible processes (the most efficient processes possible), the net change in entropy in the universe (system + surroundings) is zero. Phenomena that introduce irreversibility and inefficiency are: friction, heat transfer across finite temperature differences, free expansion.

What is the entropy change of an isothermal process?

An isothermal process is a process which takes place at constant temperature (T = constant). If we apply the definition of the entropy change, we have: This expression is valid for any thermodynamic system that undergoes an isothermal process. As a consequence, we can use it to calculate the entropy change of a heat reservoir.